Welcome to Advanced Polymer Science Lab

高分子創成科学研究室 (thinking outside of the box)



Pacifichem2015 (Honolulu, Hawaii, USA, Dec 15-20, 2015)

logo-pacifichem-2015.pngLinkIconProf. Ben Zhong Tang(香港科学技術大学)、LinkIconProf. Bin Liu (シンガポール国立大学)とともに
LinkIconAggregation Induced Emission: Materials and Applications (#444)を開催し、成功裏に終わりました。
本セッションの主要部分はACS Symposium E-book Seriesとして出版予定です。Michiya. Ben, Bin

Aggregation-Induced Enhanced (AIEnh) CD, ORD, and CPL Signals

AIEnh-CD (with AIEh-ORD)

1. H. Nakashima, M. Fujiki, J. R Koe, M. Motonaga, J. Am. Chem. Soc., 123, 1963 (2001).
2. H. Nakashima, J. R. Koe, K. Torimitsu, M. Fujiki, J. Am. Chem. Soc., 123, 4847 (2001).
3. Z.-B. Zhang, M. Fujiki, M. Motonaga, H. Nakashima, K. Torimitsu, H.-Z. Tang, Macromolecules, 35, 941 (2002).
4. H.-Z. Tang, M. Fujiki, T. Sato, Macromolecules, 35, 6439 (2002).
5. Z.-B. Zhang, M., Motonaga, M. Fujiki, C. E. McKenna, Macromolecules, 36, 6956 (2003).
6. Z.-B. Zhang, M. Fujiki, M. Motonaga, C. E. McKenna, J. Am. Chem. Soc., 125, 7878 (2003).
7. A. Ohira, M. Kunitake, M. Fujiki, M. Naito, A. Saxena, Chem. Mater., 16, 3919 (2004). (as a film state).
8. A. Ohira, K. Okoshi, M. Fujiki, M. Kunitake, M. Naito, T. Hagihara, Adv. Mater., 16, 1645 (2004). (as a film state).
9. S. Y. Kim, M. Fujiki, A. Ohira, G. Kwak, Y. Kawakami, Macromolecules, 37, 4321 (2004). (as a film state).
10. A. Saxena, G. Guo, M. Fujiki, Y. Yang, A. Ohira, K. Okoshi, M. Naito, Macromolecules, 37, 3081 (2004). (as a film state).
11. K. Terao, Y. Mori, T. Dobashi, T. Sato, A. Teramoto, M. Fujiki, Langmuir, 20, 306 (2004). (as a capsule state).
12. R. Rai, A. Saxena, A. Ohira, M. Fujiki, Langmuir, 21, 3957 (2005).
13. S. Haraguchi, T. Hasegawa, M. Numata, M. Fujiki, K. Uezu, K. Sakurai, S. Shinkai, Org. Lett., 7, 5605 (2005).
14. M. Ikeda, T. Hasegawa, M. Numata, K. Sugikawa, K. Sakurai, M. Fujiki, S. Shinkai, J. Am. Chem. Soc., 129, 3979 (2007).
15. W. Zhang, S. Ishimaru, H. Onouchi, Roopali Rai, A. Saxena, A. Ohira, M. Ishikawa, M. Naito, M. Fujiki, New J. Chem., 34, 2310 (2010).
16. M. Fujiki, Symmetry, 2, 1625 (2010).
17. W. Zhang, M. Fujiki, Z. Zhu, Chem. Eur. J. 17, 10628 (2011).
18. W. Zhang, K. Yoshida, M. Fujiki, X. Zhu, Macromolecules, 44, 5105 (2011).
19. T. G. Barclay, K. Constantopoulos, W. Zhang, M. Fujiki, J. G. Matisons, Langmuir, 28, 14172 (2012).
20. T. G. Barclay, K. Constantopoulos, W. Zhang, M. Fujiki, N. Petrovsky, J. G. Matisons, Langmuir, 29, 10001 (2013).
21. M. Fujiki, K. Yoshida, N. Suzuki, J. Zhang, W. Zhang, X. Zhu, RSC Adv., 3, 5213 (2013).
22. N. Suzuki, M. Fujiki, R. Kimpinde-Kalunga, J. R. Koe, J. Am. Chem. Soc., 135, 13073 (2013).
23. S. Yorsaeng, Y. Kato, K. Tsutsumi, A. Inagaki, B. Kitiyanan, M. Fujiki, K. Nomura, Chem. Eur. J., 21, 16764 (2015).

AIEnh-CPL (with AIEnh-CD and AIEh-ORD)

1. H.-Z. Tang, M, Fujiki, M., Motonaga, Polymer, 43, 6213 (2002). (as a film state).
2. S. Haraguchi, M. Numata, C. Li, Y. Nakano, M. Fujiki, S. Shinkai, Chem. Lett., 38, 254 (2009).
3. Y. Kawagoe, M. Fujiki, Y. Nakano, New J. Chem., 34, 637 (2010).
4. Y. Nakano, Y. Liu, M. Fujiki, Polym. Chem., 1, 460 (2010).
5. Y. Nakano, M. Fujiki, Macromolecules, 48, 7511 (2011).
6. K. Watanabe. T. Sakamoto, M. Taguchi, M. Fujiki, T. Nakano, Chem. Commun., 47, 10996 (2011). (as a film state).
7. K. Okano, M. Taguchi, M. Fujiki, T. Yamashita, Angew. Chem. Int. Ed., 50, 12474 (2011). (as a gel state).
8. Y. Nakano, F. Ichiyanagi, M. Naito, Y. G. Yang, M. Fujiki, Chem. Commun., 48, 6636 (2012).
9. M. Fujiki, A.J. Jalilah, N. Suzuki, M. Taguchi, W. Zhang, M. M. Abdellatif, K. Nomura, RSC Adv., 2, 6663 (2012).
10. M. Fujiki, Y. Kawagoe, Y. Nakano, A. Nakao, Molecules, 18, 7035 (2013).
11. T. Shiraki, Y. Tsuchiya, T. Noguchi1, S.-i. Tamaru, N. Suzuki, M. Taguchi, M. Fujiki, S. Shinkai, Chem. Asian J., 9, 218 (2014).
12. L. Wang, N. Suzuki, J. Liu, T. Matsuda, N.A.A. Rahim, W. Zhang, M. Fujiki, Z. Zhang, N. Zhou, X. Zhu, Polym. Chem., 5, 5920 (2014).
13. J. Liu, J. Zhang, S. Zhang, N. Suzuki, M. Fujiki, L. Wang, L. Li, W. Zhang, N. Zhou, X. Zhu, Polym. Chem., 5, 784 (2014).
14. K. Watanabe, Y. Koyama, N. Suzuki, M. Fujiki, T. Nakano, Polym. Chem., 5, 712 (2014). (as a film state).
15. M. Fujiki, Y. Donguri, Y. Zhao, A. Nakao, N. Suzuki, K. Yoshida, W. Zhang, Polym. Chem., 6, 1627 (2015).
16. M. Fujiki, K. Yoshida, N. Suzuki, N. A. A. Rahim, J. A. Jalil, J. Photochem. Photobiol. A: Chem. (DOI: 10.1016/j.jphotochem.2016.01.027).
17. Y. Zhao, N. A. A. Rahim, Y. Xia, M. Fujiki, B. Song, Z. Zhang, W. Zhang, X. Zhu, Macromolecules, 49, 3214 (2016). (as gel and film states).
18. N. A. A. Rahim and M. Fujiki, Polym. Chem., 7, 4618 (2016).

Surface and Interface

1. M. Fujiki, H. Tabei, K. Kurihara, Langmuir, 4, 1123 (1988). (air-water)
2. M. Fujiki, H. Tabei, Langmuir, 4, 320 (1988). (air-water)
3. K. Ebihara, S.-Y. Koshihara, M. Yoshimoto, T. Maeda, T. Ohnishi, H. Koinuma, M. Fujiki, Jpn. J. Appl. Phys., 36, L1211 (1997). (air-solid)
4. K. Ebata, K. Furukawa, N. Matsumoto, M. Fujiki, ACS, Polym. Prepr., 40(2), 157 (1999). (air-solid)
5. K. Furukawa, K. Ebata, M. Fujiki, Adv. Mater., 12, 1033 (2000). (air-solid)
6. G. Guo, M. Naito, M. Fujiki, A. Saxena, K. Okoshi, Y. Yang, M. Ishikawa, T. Hagihara, Chem. Commun., 276 (2004).
7. A. Saxena, G. Guo, M. Fujiki, Y. Yang, A. Ohira, K. Okoshi, M. Naito, Macromolecules, 37, 3081 (2004). (solid-solid)
8. A. Ohira, S.-Y. Kim, M. Fujiki, Y. Kawakami, M. Naito, G. Kwak, A. Saxena, Chem. Commun., 2705 (2006). (liquid-solid)
9. M. Naito, N. Saeki, A. Ohira, M. Fujiki, Macromolecules, 40, 648 (2007). (liquid-solid)
10. M. Ishikawa, M. Fujiki, M. Naito, Chem. Lett., 36, 304 (2007). (liquid-solid)
11. Y. Liu, T. Murao, Y. Nakano, M. Naito, M. Fujiki, Soft Matter, 4, 2396 (2008). (air-solid)
12. M. Naito, M. Fujiki, Soft Matter, 4, 211 (2008).
13. A. Nakao, M. Fujiki, Polym. J., 47, 434 (2015). (liquid-solid)

不斉の起源に学び、らせんを操る: 自然と共生する次世代の高分子科学へ向けて

38億年前、地球上に誕生した生命世界のホモキラリティーの起源をめぐる諸説にヒントを得ながら、安全・短工程・資源・エネルギー・
環境・リユース・産業応用に繋げていく、光機能共役高分子の設計・合成・分光計測解析・新機能発現を中心とする研究室です.
詳しくは、NAIST広報誌 せんたん Vol. 19, No3 (2011年1月号) pp19-20 をご覧ください。LinkIconDLはこちら

学術雑誌の表紙を飾った論文

Nor Azura Abdul Rahim and Michiya Fujiki
Aggregation-induced scaffolding: photoscissable helical polysilane generates circularly polarized luminescent polyfluorene
Polymer Chemistry (RSC), 7, 4618−4629 (2016) LinkIconLINK TOLinkIconCoverPage

Kazuki Nakabayashi, Sayaka Kitamura, Nozomu Suzuki, Sibo Guo, Michiya Fujiki, Yoshitane Imai
Non-Classically Controlled Signs in a Circularly Polarised Luminescent Molecular Puppet:
The Importance of the Wired Structure Connecting Binaphthyl and Two Pyrenes
European Journal of Organic Chemistry (Wiley), 64-69 (2016) LinkIconLINK TOLinkIconCoverPage

Tomoki Nishikawa, Nobuo Tajima, Mizuki Kitamatsu, Michiya Fujiki, Yoshitane Imai
Circularly polarised luminescence and circular dichroism of L- and D-oligopeptides with multiple pyrenes
Organic & Biomolecular Chemistry (RSC), 13, 11426-11431 (2015).LinkIconLINK TOLinkIconCoverPage

Tomoyuki Amako, Kazuki Nakabayashi, Nozomu Suzuki, Sibo Guo, Nor Azura Abdul Rahim, Takunori Harada, Michiya Fujiki, Yoshitane Imai
Pyrene Magic: Chiroptical Enciphering and Deciphering 1,3-Dioxolane Bearing Two Wirepullings to Drive Two Remote Pyrenes
Chemical Communications (RSC), 51, 8237−8240 (2015). LinkIconLINK TOLinkIconCoverPage

Tomoyuki Amako, Kazuki Nakabayashi, Atsushi Sudo, Michiya Fujiki, Yoshitane Imai
Solid-State Circularly Polarised Luminescence of Atrope Fluorophores Embedded in myo-Inositol-Containing Polyurethanes
Organic & Biomolecular Chemistry (RSC), 13, 2913-2918 (2015). LinkIconLINK TOLinkIconCoverPage

Tomoyuki Amako, Kazuki Nakabayashi, Tadashi Mori, Yoshihisa Inoue, Michiya Fujiki, Yoshitane Imai
Sign Inversion of Circularly Polarized Lluminescence by Geometry Manipulation of Four Naphthalene Units Introduced into a Tartaric Acid Scaffold
Chemical Communications (RSC), 50, 12836-12839 (2014).LinkIconLINK TOLinkIconCoverPage

Laibing Wang, Nozomu Suzuki, Jiangfei Liu, Takashi Matsuda, Nor Azura Abdul Rahim, Wei Zhang, Michiya Fujiki, Zhengbiao Zhang, Nianchen Zhou, Xiulin Zhu
Limonene Induced Chiroptical Generation and Inversion during Aggregation of Achiral Polyfluorene Analogs: Structure-Dependence and Mechanism
Polymer Chemistry (RSC), 5, 5920-5927 (2014) LinkIconLINK TOLinkIconCoverPage

Kazuki Nakabayashi, Tomoyuki Amako, Nobuo Tajima, Michiya Fujiki, Yoshitane Imai
Nonclassical Dual Controlling Circularly Polarized Luminescence Modes of Binaphthyl–Pyrene Organic Fluorophores
in Fluidic and Glassy Media
Chemical Communications (RSC), 50, 13228-13230 (2014).LinkIconLINK TOLinkIconCoverPage

Masato Hirayama, Yuhei Kobayashi, Yuki Tanaka, Tomohiro Sato, Takunori Harada, Nobuo Tajima,
Reiko Kuroda, Michiya Fujiki, Yoshitane Imai
Chiral Optical Properties of Phenyloxazoline Derivatives that Appear Only in the Solid State
European Journal of Organic Chemistry (Wiley), 4, 719-724 (2014).LinkIconLINK TOLinkIconCoverPage

Yoko Kitayama, Tomoyuki Amako, Nozomu Suzuki, Michiya Fujiki, Yoshitane Imai
Enhancing Circularly Polarised Luminescence by Extending the π-Conjugation of Axially Chiral Compounds
Organic & Biomolecular Chemistry (RSC), 12, 4342-4346 (2014). LinkIconLINK TOLinkIconCoverPage

Naoya Taniguchi, Ryutaro Shimomaki, Amako Ryutaro, Sato Tomoyuki, Tomohiro Tokutome, Nobuo Tajima,
Reiko Kuroda, Michiya Fujiki, Yoshitane Imai
Preparation of a Spontaneously Resolved Chiral Fluorescent System Containing 4-(2-Arylethynyl)benzoic Acid
Asian Journal of Organic Chemistry (Wiley-VCH), 2, 681-687 (2013) .LinkIconLINK TOLinkIconCoverPage

Makoto Taguchi, Nozomu Suzuki, Michiya Fujiki
Intramolecular CH/π interaction of Poly(9,9-dialkylfluorene)s in Solutions: Interplay of the Fluorene Ring and Alkyl Side Chains
Revealed by 2D 1H-1H NOESY NMR and 1D 1H NMR Experiments
Polymer Journal (NPG), 45, 1047-1057 (2013). LinkIconLINK TOLinkIconCoverPage

Yoko Nakano, Fumiko Ichiyanagi, Masanobu Naito, Yonggang Yang, Michiya Fujiki
Chiroptical Generation and Inversion during the Mirror-symmetry-breaking Aggregation of Dialkylpolysilanes due to Limonene Chirality
Chemical Communications (RSC), 48, 6636-6638 (2012).LinkIconLINK TOLinkIconCoverPage

Michiya Fujiki, Yuji Fujimoto, Anubhav Saxena, Takuma Kawabe, Giseop Kwak
Air-stable Poly(3,3,3-trifluoropropylsilyne) Homo- and Copolymers
Polymer Chemistry (RSC), 3, 3256-3265(2012).LinkIconLINK TOLinkIconCoverPage

Takaya Kimoto, Nobuo Tajima, Michiya Fujiki, Yoshitane Imai
Control of Circularly Polarized Luminescence by Using Open- and Closed-Type Binaphthyl Derivatives with the Same Axial Chirality
Chemistry an Asian Journal (Wiley-VCH), 7, 2836-2841 (2012).LinkIconLINK TOLinkIconCoverPage

Kunihiko Okano, Makoto Taguchi, Michiya Fujiki, Takashi Yamashita
Circularly Polarized Luminescence of Rhodamine B in a Supramolecular Chiral Medium Formed by a Vortex Flow
Angewandte Chemie International Edition (Wiley-VCH), 50, 12474−12477(2011).LinkIconLINK TOLinkIconFrontisepiece

Yoko Nakano, Yang Liu, Michiya Fujiki
Ambidextrous Circular Dichroism and Circularly Polarised Luminescence from Poly(9,9-di-n-decylfluorene) by Terpene Chirality Transfer
Polymer Chemistry (RSC), 1, 460–469 (2010).LinkIconLINK TOLinkIconCoverPage

Yoshifumi Kawagoe, Michiya Fujiki, Yoko Nakano
Limonene magic: Noncovalent Molecular Chirality Transfer Leading to Ambidextrous Circularly Polarised Luminescent π-Conjugated Polymers
New Journal of Chemistry (RSC), 34, 637–647 (2010).LinkIconLINK TOLinkIconHotNews

Michiya Fujiki and Anubhav Saxena
Nonclassical Forces: Seemingly Insignificant but a Powerful Tool to Control Macromolecular Structures
Journal of Polymer Science Part A: Polymer Chemistry (Wiley), 46, 4637–4650 (2008).LinkIconLINK TOLinkIconCoverPage

Takuma Kawabe, Masanobu Naito, Michiya Fujiki,
Polysilane Organogel with Hierarchical Structures Formed by Weak Intra-/Inter-chain Si/FC and Van der Waals Interactions
Polymer Journal (SPSJ), 40, 317-326 (2008).LinkIconLINK TOLinkIconCoverPage

Giseop Kwak, Akiko Takagi, Michiya Fujiki
Energy Transfer from Locally Excited π* to Charge Transfer Ground States in a Silylene–π Hetero-Junction Polymer
Macromolecular Rapid Communications (Wiley-VCH), 27, 1561–1564 (2006).LinkIconLINK TOLinkIconCoverPage

研究ハイライト

時間反転対称性の破れを操る:蛍光分子に不斉情報を暗号化し、光で暗号を解読

第2次世界大戦中、軍事機密であるアナログ音声情報を暗号化するためにパルスコード変調(PCM)法による暗号を用いたデジタル信号伝送方式がAT&T ベル研究所で開発された。それ以来今日に至るまで、有線・無線を問わず、盗聴されやすいアナログ信号から盗聴されにくいデジタル信号による情報の伝送が一般的になり、情報の暗号化と伝送に関する種々の方式が提案されてきた。1984年、Charles H. Bennett (IBM)とGiles Brassard (Université de Montréal)は、LinkIconBB84と呼ばれる強力な量子暗号プロトコルを提案した。AliceとBobが外部から盗聴されない量子暗号によって接続し、それから会話を始める話に例えられている。最近、量子暗号を用いた高速・大容量・長距離コヒーレント光通信 (40 Gbit/sec, 480 Km)に成功した (2014年9月, 東北大学 電気通信研究所 中沢正隆教授ら)。そこで、時間反転対称性の破れという物理法則に則り、情報とエントロピー、非平衡開放系熱力学、フランク=コンドンの原理を考慮した、不斉情報の暗号化を可能にする蛍光分子を設計し、光による暗号解読法を提示した。
Tomoyuki Amako, Kazuki Nakabayashi, Nozomu Suzuki, Sibo Guo, Nor Azura Abdul Rahim, Takunori Harada, Michiya Fujiki, Yoshitane Imai
Pyrene Magic: Chiroptical Enciphering and Deciphering 1,3-Dioxolane Bearing Two Wirepullings to Drive Two Remote Pyrenes
Chemical Communications, 51, 8237−8240 (2015) LinkIconLink

不斉の常識に挑む: 回転する光の励起波長制御により円偏光発光性高分子の左右が反転

らせん高分子の左右の作り分けは円偏光源の波長(エネルギー)で決定され、円偏光源の回転方向だけでは決められないことを発見した。同じ右(左)回転の円偏光源を照射しながら、波長の長い可視光照射では右(左)らせん高分子、波長の短い紫外光照射では左(右)らせん高分子ができた。
LinkIcon報道発表 毎日新聞(H27.3.4朝刊27面)、日刊工業新聞(H27.1.9朝刊25面)、日経産業新聞(H27.1.15朝刊10面)、化学工業日報(H27.1.20朝刊6面)、電子デバイス新聞(H27.1.22朝刊9面)などで取り上げられた。
Michiya Fujiki, Yuri Donguri, Yin Zhao, Ayako Nakao, Nozomu Suzuki, Kana Yoshida, Wei Zhang
Photon Magic: Chiroptical Polarisation, Depolarisation, Inversion, Retention and Switching of Non-photochromic Light-emitting Polymer
in Optofluidic Medium
Polymer Chemistry (RSC), 6, 1627-1638 (2015)LinkIconLINK

不斉化学の最前線: キラル化学ーその起源から最新のキラル材料研究まで (日本化学会編:化学同人) を出版

キラル化学ーその起源から最新のキラル材料研究までー編集・監修: 八島栄次、門出健次、高田十志和
(日本化学会編、CSJカレントレビューシリーズ 第14巻), 化学同人 2013年10月.LinkIconLINK
キラリティにかかわる研究は,多方面にわたって広がりを見せており,不斉の発生や起源に遡る研究やキラリティを検知する分析装置の開発,創薬と密接に関係する不斉合成,光学分割など,基礎研究から機能開発,応用展開まで多種多様に繰り広げられている。本書では,キラリティに関する最先端の研究とその動向を中心に紹介。藤木は「PartII, 9章らせん高分子と不斉の起源」と「キラリティーにかかわるノーベル物理学賞」を執筆。

共役高分子の集大成: 最新の実験手引書がイギリス王立化学会から出版...Conjugated Polymers-A Practical Guide to Synthesis

Michiya Fujiki, Chapter 13: Si-Si Bond Polymers, Oligomers, Molecules, Surface, and Materials,
in "Conjugated Polymers", Klaus Mullen, John R Reynolds, Toshio Masuda (Eds)
ISBN: 978-1-84973-799-9 (Copyright: 2013) Price: £159.99 LinkIconLINK

不斉の常識に挑む: らせん転写により蛍光量子収率71%の円偏光発光性超分子ポリマーが発生

Tomohiro Shiraki, Youichi Tsuchiya, Takao Noguchi, Shun-ichi Tamaru, Nozomu Suzuki, Makoto Taguchi, Michiya Fujiki, Seiji Shinkai
Creation of Circularly Polarized Luminescence from an Achiral Polyfluorene Derivative through Complexation with
Helix-forming Polysaccharides: Importance of the Meta-Linkage Chain for Helix Formation
Chemistry-Asian Journal, 9, 218-222 (2014).LinkIconLINK

不斉の常識に挑む: 渦研究の先駆者ダ•ビンチから500年後, 撹拌渦で円偏光発光度(3%)の蛍光色素-高分子ゲルの発生/反転/固定に成功

Kunihiko Okano, Makoto Taguchi, Michiya Fujiki, Takashi Yamashita
Circularly Polarized Luminescence of Rhodamine B in a Supramolecular Chiral Medium Formed by a Vortex Flow
Angewandte Chemie International Edition, 50, 12474-12477(2011).LinkIconLINK

不斉の極限に挑む: 円偏光発光度35%, 蛍光量子収率53%の光学活性高分子を無触媒(常温,常圧,収率100%,1分)で合成

Yoko Nakano, Michiya Fujiki,
Circularly Polarized Light Enhancement by Helical Polysilane Aggregates Suspension in Organic Optofluids
Macromolecules, 44, 7511-7519 (2011). LinkIconLINK

不斉の常識に挑む: CH/pi相互作用による円偏光発光性2/1らせん超分子の自然分晶...Asian J. Org. Chem.の表紙に、WileyのHotNewsで紹介

Naoya Taniguchi, Ryutaro Shimomaki, Tomoyuki Amako, Tomohiro Sato, Hayato Tokutome, Nobuo Tajima, Reiko Kuroda,
Michiya Fujiki, Yoshitane Imai
Preparation of a Spontaneously Resolved Chiral Fluorescent System Containing 4-(2-Arylethynyl)benzoic Acid
Asian Journal of Organic Chemistry (Wiley-VCH) 2, 681-687 (2013). LinkIconFreeDLLinkIconWiley News

不斉の常識に挑む: 自発的鏡像対称性の破れか ?

1. M. Fujiki. Experimental Tests of Parity Violation at Helical Polysilylene Level, Macromol. Rapid Commun., 22, 669-674 (2001).LinkIconLINK
2. M. Fujiki, Mirror Symmetry Breaking of Silicon Polymers - From Weak Bosons to Artificial Helix, Chem. Rec., 9, 271-298 (2009).LinkIconLINK
3. M. Fujiki, Mirror Symmetry Breaking in Helical Polysilanes: Preference between Left and Right of Chemical and Physical Origin, Symmetry, 2, 1625-1652 (2010).LinkIconLINK
4. Y. Nakano, M. Fujiki, Circularly Polarized Light Enhancement by Helical Polysilane Aggregates Suspension in Organic Optofluids, Macromolecules, 44, 7511-7519 (2011). LinkIconLINK
5. M. Fujiki, A. J. Jalilah, N. Suzuki, M. Taguchi, W. Zhang, M. M. Abdellatif, K. Nomura, Chiral optofluidics: Gigantic circularly polarized light enhancement of all-trans-poly(9,9-di-n-octylfluorene-2,7-vinylene) during mirror-symmetry-breaking aggregation by optically tuning fluidic media, RSC Adv., 2, 6663-6671 (2012).LinkIconLINK
6. M. Fujiki, K. Yoshida, N. Suzuki, J. Zhang, W. Zhang, X. Zhu, Mirror Symmetry Breaking and Restoration within μm-Sized Polymer Particles in Optofluidic Media by Pumping Circularly Polarised Light, RSC Adv., 3, 5213-5219 (2012).LinkIconLINK
7. M. Fujiki, Y. Kawagoe, Y. Nakano, A. Nakao, Mirror-Symmetry-Breaking in Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-biphenyl] (PF8P2) is Susceptible to Terpene Chirality, Achiral Solvents, and Mechanical Stirring, Molecules, 18, 7035-7057 (2013).LinkIconLINK
8. H. Kim, D. Lee, S. Lee, N. Suzuki, M. Fujiki, C.-L. Lee, G. Kwak, Optically Active Conjugated Polymer from Solvent Chirality Transfer Polymerization in Monoterpenes, Macromol. Rapid Commun. 34, 1471-1479 (2013).LinkIconLINK
9. J. Liu, J. Zhang, S. Zhang, N. Suzuki, M. Fujiki, L. Wang, L. Li, W. Zhang, N. Zhou, X. Zhu, Chiroptical Generation and Amplication of Hyperbranched π-Conjugated Polymers in Aggregation States Driven by Limonene Chirality, Polym. Chem., 5, 784-791 (2014).LinkIconLINK

解説論文/記事として、
1. 藤木道也, らせんが語りかける世界:自然界の左右非対称性を解き明かす糸口となるか? 現代化学 ((東京化学同人) 6月号 17-23 (2006) .
2. 藤木道也, 左右非対称なキラリティ階層構造, 国武豊喜(監修) 自己組織化ハンドブック, NTS出版 (東京), 258-262. (2009).
3. 藤木道也, らせん構造カイラリティと鏡像対称性の破れ, パリティ(丸善)5月号, 32-34 (2011).
4. 藤木道也, PartII, 9章 らせん高分子と不斉の起源, 編集・監修: 八島栄次、門出健次、高田十志和: キラル化学ーその起源から最新のキラル材料研究まで
  (日本化学会編、CSJカレントレビューシリーズ 第14巻、(化学同人, 2013年10月).

不斉の常識に挑む: 数理モデルと精密分光計測解析によりらせん高分子の光学活性反転現象を解析...J. Am. Chem. Soc. に掲載

Nozomu Suzuki, Michiya Fujiki, Ruth Kimpinde-Kalunga, Julian R. Koe
Chiroptical Inversion in Helical Si-Si Bond Polymer Aggregates
Journal of the American Chemical Society, 135, 13073-13079 (2013). LinkIconLINK

化学の常識に挑む: パイ共役高分子の分子内CH/pi相互作用を検出...Polymer Journal の表紙に

Makoto Taguchi, Nozomu Suzuki, Michiya Fujiki
Intramolecular CH/π interaction of Poly(9,9-dialkylfluorene)s in Solutions: Interplay of the Fluorene Ring and Alkyl Side Chains Revealed by 2D 1H-1H NOESY NMR and 1D 1H NMR Experiments
Polymer Journal, 45, 1047-1057 (2013).LinkIconLINK

不斉の起源に挑む: 光による絶対不斉合成...円偏光励起による不斉高分子の発生と制御に成功

Michiya Fujiki, Kana Yoshida, Nozomu Suzuki, Jian Zhang, Wei Zhang, Xiulin Zhu
Mirror Symmetry Breaking and Restoration within μm-Sized Polymer Particles in Optofluidic Media by Pumping Circularly Polarised Light
RSC Advances, 3, 5213-5219 (2013).LinkIconLINKLinkIconLINK

化学の常識に挑む: 酸素や水の暴露に対して極めて安定な紫外可視発光性ケイ素高分子を実現

Michiya Fujiki, Yuji Fujimoto, Anubhav Saxena, Takuma Kawabe, Giseop Kwak
Air-stable poly(3,3,3-trifluoropropylsilyne) homo- and copolymers
Polymer Chemistry, 3, 3256-3265(2012) (研究ハイライトとしてcoverに採用)LinkIconLINK

不斉の常識に挑む: 巨大な円偏光吸収・発光特性を持つ青色発光高分子の無触媒合成(常温-常圧, 収率100%, 1分)に成功

Michiya Fujiki, Abd Jalil Jalilah, Nozomu Suzuki, Makoto Taguchi, Wei Zhang, Mohamed Mehawed Abdellatif and Kotohiro Nomura,
Chiral optofluidics: Gigantic circularly polarized light enhancement of all-trans-poly(9,9-di-n-octylfluorene-2,7-vinylene) during mirror-symmetry-breaking aggregation by optically tuning fluidic media
RSC Advances, 2, 6663-6671 (2012).LinkIconLINK

不斉の常識に挑む: 巨大な円偏光吸収・発光特性を持つ緑色発光高分子の無触媒合成(常温-常圧, 収率100%, 1分)に成功

Yoshifumi Kawagoe, Michiya Fujiki and Yoko Nakano
Limonene magic: noncovalent molecular chirality transfer leading to ambidextrous circularly polarised luminescent π-conjugated polymers
New Journal of Chemistry, 34, 637-647 (2010).LinkIconLINK

不斉の起源に挑む: 巨大な円偏光吸収・発光特性を持つ紫外発光高分子の無触媒合成(常温-常圧, 収率100%, 1分)に成功

Yoko Nakano, Fumiko Ichiyanagi, Masanobu Naito, Yonggang Yang, Michiya Fujiki
Chiroptical Generation and Inversion During The Mirror-Symmetry-Breaking Aggregation of Dialkylpolysilanes due to Limonene Chirality
Chemical Communications, 48, 6636-6638 (2012) (Cover Page 6月号に掲載)LinkIconLINKLinkIcon報道発表