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{\info
{\title Laboratory for Supramolecular Science (Hirota Lab.) Original papers}}\paperw12240\paperh15840\vieww21980\viewh12420\viewkind0
\deftab720

\itap1\trowd \taflags0 \trgaph108\trleft-108 \trbrdrt\brdrnil \trbrdrl\brdrnil \trbrdrr\brdrnil 
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\clvertalt \clshdrawnil \clwWidth11672\clftsWidth3 \clbrdrt\brdrnil \clbrdrl\brdrnil \clbrdrb\brdrnil \clbrdrr\brdrnil \clpadl0 \clpadr0 \gaph\cellx5760
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\cf2 \nestcell 
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\f3\fs26 \cf0 A Bioinspired bifunctional catalyst: an amphiphilic organometallic catalyst for ring-closing metathesis forming liquid droplets in aqueous media
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\f4\i Chem. Commun.
\f0\i0  2024, 60(18), 7979-7982. \
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\f4\i Inorg. Chem.
\f0\i0  2024, 63(18), 8026-8037. \uc0\u8232 \u8232 \
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\fs20 \super 2+
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\f4\i N
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\f0\i0 '-bis(2-quinolylmethyl)-
\f4\i N
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\f4\i N
\f0\i0 '-dimethyl-1,2-phenylenediamine derivatives.\uc0\u8232 Mikata, Y.; Kawakami, K.; Nagaoka, M.; Shoji, S.; Konno, H.; Matsuo, T. 
\f4\i Inorg. Chim. Acta.
\f0\i0  2024, 565(24), 121968(1)-121968(11). \expnd0\expndtw0\kerning0
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\outl0\strokewidth0 \strokec2 Resonance Raman Studies on Heme Ligand Stretching Modes of Methionine80-Depleted Cytochrome c: Fe\uc0\u8722 His, Fe\u8722 O2, and O\u8722 O Stretching Modes\u8232 Zhang, M.; Tai, H.; Yanagisawa, S.; Yamanaka, M.; Ogura, T.; Hirota, S. 
\f4\i J. Phys. Chem. B 
\f0\i0 2023, 127 (11), 2442-2449.\uc0\u8232 \u8232 \
\ls2\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Conformation state-specific monobodies regulate the functions of flexible proteins through conformation trapping\uc0\u8232 Nakamura, I.; Amesaka, H.; Hara, M.; Yonezawa, K.; Okamoto, K.; Kamikubo, H.; Tanaka, S.-I.; Matsuo, T. 
\f4\i Protein Sci.
\f0\i0  2023, 32 (12), e4813(1)-e4813(16).\uc0\u8232 \u8232 \
\ls2\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Structural and thermodynamic insights into antibody light chain tetramer formation through 3D domain swapping.\uc0\u8232 Sakai, T.; Mashima, T.; Kobayashi, N.; Ogata, H.; Duan, L.; Fujiki, R.; Hengphasatporn, K.; Uda, T.; Shigeta, Y.; Hifumi, E.; Hirota, S. 
\f4\i Nat. Commun.
\f0\i0  2023, 14, 7807(1)-7807(12). \uc0\u8232 \u8232 \
\ls2\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Reactivity regulation for olefin metathesis-catalyzing ruthenium complexes with sulfur atoms at the terminal of 2-alkoxybenzylidene ligands.\uc0\u8232 Kinugawa, T.; Matsuo, T. 
\f4\i Dalton Trans.
\f0\i0  2023, 52 (27), 9499-9508. \uc0\u8232 \u8232 \
\ls2\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Effect of methoxy substituents on fluorescent Zn2+/Cd2+ selectivity of bisquinoline derivatives with a N,N'-dimethylalkanediamine skeleton\uc0\u8232 Mikata, Y.; Tanaka, M.; Yasuda, S.; Tsuruta, A.; Hagiwara, T.; Konno, H.; Matsuo, T. 
\f4\i Daltron Trans.
\f0\i0  2023, 52(22), 11375-11388. 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40
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\f2\b \cf2 Book Chapter
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\outl0\strokewidth0 \strokec2 AlphaFold
\f1 \'8e\'9e\'91\'e3\'82\'cc\'90\'b6\'90\'ac\'83\'82\'83\'66\'83\'8b\'82\'aa\'90\'67\'8b\'df\'82\'c9\'82\'b7\'82\'e9\'83\'5e\'83\'93\'83\'70\'83\'4e\'8e\'bf\'90\'dd\'8c\'76\'81\'69\'83\'66\'83\'55\'83\'43\'83\'93\'81\'6a
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\f1 \'8f\'ac\'97\'d1\'81\'40\'92\'bc\'96\'e7\'81\'41\'8d\'b2\'8b\'76\'8a\'d4\'81\'40\'8d\'71\'96\'e7
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\f1 \'8e\'c0\'8c\'b1\'88\'e3\'8a\'77
\f0 .10
\f1 \'8c\'8e\'8d\'86
\f0 \uc0\u8232 \u8232 
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\ls3\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Protein Cages and Nanostructures Constructed from Protein Nanobuilding Blocks\uc0\u8232 Kobayashi, M.; Arai, R.\u8232 "Protein Cages Design, Structure, and Applications; pp. 79-94, Hamana, New York, NY. \
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\outl0\strokewidth0 \strokec2 Structural and Spectroscopic Characterization of CO Inhibition of [NiFe]-Hydrogenase from Citrobacter sp. S-77\uc0\u8232 Imanishi, T.; Nishikawa, K.; Taketa, M.; Higuchi, K.; Tai, H.; Hirota, S.; Hojo, H.; Kawakami, T.; Hataguchi, K.; Matsumoto, K.; Ogata, H.; Higuchi, Y. 
\f4\i Acta Crystal. F
\f0\i0  2022, 78(2), 66-74.\uc0\u8232 \u8232 \
\ls4\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Heme-Bound Tyrosine Vibrations in Hemoglobin M: Resonance Raman, Crystallography and DFT Calculation\uc0\u8232 Nagatomo, S.; Shoji, M.; Terada, T.; Nakatani, K.; Shigeta, Y.; Hirota, S.; Yanagisawa, S.; Kubo, M.; Kitagawa, T.; Nagai M.; Ohki, M; Park, S.-Y.; Shibayama N. 
\f4\i Biophys. J.
\f0\i0  2022, 121(14), 2767-2780.\uc0\u8232 \u8232 \
\ls4\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Structural Region Essential for Amyloid Fibril Formation in Cytochrome c Elucidated by Optical Trapping\uc0\u8232 Hirota, S.; Chiu, C.-L.; Chang, C.-J.; Lo, P.-H.; Chen, T.; Yang, H.; Yamanaka, M.; Mashima, T.; Xie, C.; Masuhara, H.; Sugiyama, T. 
\f4\i Chem. Commun.
\f0\i0  2022, 58(92), 12839-12842.\uc0\u8232 \u8232 \
\ls4\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Cd2+-selective fluorescence response of TQEN (N,N,N',N'-tetrakis(2-quinolylmethyl)ethylenediamine) derivatives bearing ether oxygen-binding site\uc0\u8232 Mikata, Y.; Kaneda, M.; Yonemura, S.; Akedo, M.; Konno, H.; Matsuo, T. 
\f4\i Daltron Trans.
\f0\i0  2022, 51, 17170-17179.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews 
\f0\b0 (International achievements only)\
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\outl0\strokewidth0 \strokec2 Second and Outer Coordination Sphere Effects in Nitrogenase, Hydrogenase, Formate Dehydrogenase, and CO Dehydrogenase\uc0\u8232 Stripp, S. T.; Duffus, B.R.; Fourmond, V.; L\'e9ger, C.; Leimk\'fchler, S.; Hirota, S.; Hu., Y.; Jasniewsk, A.; Ogata, H.; Ribbe, M. 
\f4\i Chem. Rev.
\f0\i0  2022, 122(14), 11900-11973. \uc0\u8232 \u8232 \
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\f2\b \cf2 2021
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\outl0\strokewidth0 \strokec2 Rational Design of Metal-Binding Sites in Domain-Swapped Myoglobin Dimers \uc0\u8232 Nagao, S.; Idomoto, A.; Shibata, N.; Higuchi, Y.; Hirota, S. 
\f4\i J. Inorg. Biochem.
\f0\i0  2021, 217, 111374.\uc0\u8232 \u8232 \
\ls6\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Construction of Ferritin Hydrogels Utilizing Subunit\'96Subunit Interactions\uc0\u8232 Yamanaka, M.; Mashima, T.; Ogihara, M.; Okamoto, M.; Uchihashi, T.; Hirota, S. 
\f4\i PLoS One
\f0\i0  2021, 16(11), e0259052.\uc0\u8232 \u8232 \
\ls6\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Experimental and Theoretical Study on Converting Myoglobin into a Stable Domain-Swapped Dimer by Utilizing a Tight Hydrogen Bond Network at the Hinge Region\uc0\u8232 Xie, C.; Shimoyama, H.; Yamanaka, M.; Nagao, S.; Komori, H.; Shibata, N.; Higuchi, Y.; Shigeta, Y.; Hirota, S. 
\f4\i RSC Advances
\f0\i0  2021, 11(5), 37604-37611.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews 
\f0\b0 (International achievements only)\
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\outl0\strokewidth0 \strokec2 New Aspects of Cytochrome c: 3D Domain Swapping, Membrane Interaction, Peroxidase Activity, and Met80 Sulfoxide Oxidation\uc0\u8232 Hirota, S.; Nagao, S. 
\f4\i Bull. Chem. Soc. Jpn. (Award Account)
\f0\i0  2021, 94(1), 170-182 (Featured on Inside Cover).\uc0\u8232 \u8232 \
\ls7\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Proton Transfer Mechanisms in Bimetallic Hydrogenases\uc0\u8232 Tai, H.; Hirota, S.; Stripp, S. 
\f4\i Acc. Chem. Res.
\f0\i0  2021, 54(1), 232-241.\uc0\u8232 \u8232 \
\ls7\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Functionalization of Ruthenium Olefin-metathesis Catalysts for Interdisciplinary Studies in Chemistry and Biology\uc0\u8232 Matsuo, T. 
\f4\i Catalysts
\f0\i0  2021, 11(3), 359(1)-359(25) (special issue on "Converging Chemistry and Biology: Chemoenzymatic Cascade Reactions and Biohybrid Catalysts").\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Functionalization of Hoveyda-Grubbs-type Complexes for Application to Biomolecules \uc0\u8232 Matsuo, T.
\f4\i J. Synth. Org. Chem. Jpn. (in Japanese) 
\f0\i0 2021, 79(4), 311-321.\uc0\u8232 \u8232 \
\ls7\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Use of 3D Domain Swapping in Constructing Supramolecular Metalloproteins\uc0\u8232 Hirota, S.; Mashima, T.; Kobayashi, N. 
\f4\i Chem. Commun. (Future Article)
\f0\i0  2021, 57(91), 12074-12086.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Regioselective Chemical Modification of Cysteine Residues on Protein Surfaces Focusing on Local Environment around the Conjugation Site\uc0\u8232 Miyake, T.; Tamaki, R.; Asanuma, M.; Fukada, Y.; Hirota, S.; Matsuo, T. 
\f4\i Bioconjugate Chem.
\f0\i0  2020, 31(3), 794-802.\uc0\u8232 \u8232 \
\ls8\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 3D Domain Swapping of Azurin from Alcaligenes xylosoxidans\uc0\u8232 Cahyono, R. N.; Yamanaka, M.; Nagao, S.; Shibata, N.; Higuchi, Y.; Hirota, S. 
\f4\i Metallomics
\f0\i0  2020, 12(3), 337-345. (Featured on \'93Front Cover\'94)\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Thermodynamic Control of Domain Swapping by Modulating Helical Propensity in the Hinge Region of Myoglobin\uc0\u8232 Nagao, S.; Suda, A.; Kobayashi, H.; Shibata, N.; Higuchi, Y.; Hirota, S. 
\f4\i Chem. Asian J.
\f0\i0  2020, 15(11), 1743-1749. (Selected as \'93Very Important Paper\'94)\uc0\u8232 \u8232 \
\ls8\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Second-Coordination Sphere Effects on the Reactivities of Hoveyda\'96Grubbs-Type Catalysts: A Ligand Exchange Study Using Phenolic Moiety-Functionalized Ligands\uc0\u8232 Jatmika, C.; Goshima, K.; Wakabayashi, K.; Akiyama, N.; Hirota, S.; Matsuo, T. 
\f4\i Dalton Trans.
\f0\i0  2020, 49(33), 11618-11627.\uc0\u8232 \u8232 \
\ls8\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Ligand Exchange Strategy for Delivery of Ruthenium Complex Unit to Biomolecules Based on Ruthenium-Olefin Interactions\uc0\u8232 Jatmika, C.; Wakabayashi, K.; Tamaki, R.; Nakamura, I.; Akiyama, N.; Hirota, S.; Yamaguchi, H.; Matsuo, T. 
\f4\i Chem. Lett.
\f0\i0  2020, 49(12), 1490-1493.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews 
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\outl0\strokewidth0 \strokec2 Mechanism and Application of the Catalytic Reaction of [NiFe] Hydrogenase: Recent Developments\uc0\u8232 Tai, H.; Hirota, S. 
\f4\i ChemBioChem (Concept)
\f0\i0  2020, 21(11), 1573-1581. (Selected as \'93Very Important Paper\'94)\uc0\u8232 \
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\outl0\strokewidth0 \strokec2 Conferment of CO-controlled Dimer\'96Monomer Transition Property to Thermostable Cytochrome 
\f4\i c
\f0\i0 ' by Mutation in the Subunit\'96Subunit Interface\uc0\u8232 Yamanaka, M.; Nakayama, R.; Fujii, S.; Wakai, S.; Sambongi, Y.; Hirota, S. 
\f4\i Bull. Chem. Soc. Jpn.
\f0\i0  2019, 92(3), 702-709.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Construction of a Quadrangular Tetramer and a Cage-Like Hexamer from Three-Helix Bundle-Linked Fusion Proteins\uc0\u8232 Miyamoto, T.; Hayashi, Y.; Yoshida, K.; Watanabe, H.; Uchihashi, T.; Yonezawa, K.; Shimizu, N.; Kamikubo, H.; Hirota, S. 
\f4\i ACS Synth. Biol.
\f0\i0  2019, 8(5), 1112-1120.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Domain-Swapping Design by Polyproline Rod Insertion\uc0\u8232 Shiga, S.; Yamanaka, M.; Fujiwara, W.; Hirota, S.; Goda, S.; Makabe, K. 
\f4\i ChemBioChem
\f0\i0  2019, 20(19), 2454-2457.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Protein Surface Charge Effect on 3D Domain Swapping in Cells for 
\f4\i c
\f0\i0 -type Cytochromes\uc0\u8232 Yang, H.; Yamanaka, M.; Nagao, S.; Yasuhara, K.; Shibata, N.; Higuchi, Y.; Hirota, S. 
\f4\i Biochim. Biophys. Acta-Proteins Proteom.
\f0\i0  2019, 1867(11),140265\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Cysteine SH and Glutamate COOH Contributions to [NiFe] Hydrogenase Proton Transfer Revealed by Highly Sensitive FTIR Spectroscopy\uc0\u8232 Tai, H.; Nishikawa, K.; Higuchi, Y.; Mao, Z.-w.; Hirota, S. 
\f4\i Angew. Chem. Int. Ed.
\f0\i0  2019, 58(38),13285-13290.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Determination of Proton Concentration at Cardiolipin-Containing Membrane Interfaces and Its Relation with the Peroxidase Activity of Cytochrome 
\f4\i c
\f0\i0 \uc0\u8232 Parui, P. P.; Sarakar, Y.; Majumder, R.; Das, S.; Yang, H.; Yasuhara, K.; Hirota, S. 
\f4\i Chem. Sci.
\f0\i0  2019, 10(39), 9140-9051.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews 
\f0\b0 (International achievements only)\
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\outl0\strokewidth0 \strokec2 Oligomerization of Cytochrome 
\f4\i c
\f0\i0 , Myoglobin, and Related Heme Proteins by 3D Domain Swapping\uc0\u8232 Hirota, S. 
\f4\i J. Inorg. Biochem.
\f0\i0  2019, 194, 170-179.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Recent Developments on Creation of Artificial Metalloenzymes\uc0\u8232 Matsuo, T.; Miyake, T.; Hirota, S. 
\f4\i Tetrahedron Lett.
\f0\i0  2019, 60, 151226 (8 pages).\uc0\u8232 \u8232 \
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\f2\b \cf2 2018
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\outl0\strokewidth0 \strokec2 Theoretical Analysis of the Domain-Swapped Dimerization of Cytochrome 
\f4\i c
\f0\i0 : An MD and 3D-RISM Approach\uc0\u8232 Yoshida, N.; Higashi, M.; H. Motoki H.; Hirota, S. 
\f4\i J. Chem. Phys.
\f0\i0  2018, 148(2), 025102 (7 pages).\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Global Structural Flexibility of Metalloproteins Regulates Reactivity of Transition Metal Ion in the Protein Core: An Experimental Study Using Thiol-subtilisin as a Model Protein\uc0\u8232 Matsuo, T.; Kono, T.; Shobu, I.; Ishida, M.; Gonda, K.; Hirota, S. 
\f4\i Eur. J. Chem.
\f0\i0  2018, 24(11), 2767-2775.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Oxidative Modification of Methionine80 in Cytochrome 
\f4\i c
\f0\i0  by Reaction with Peroxides\uc0\u8232 Nugraheni, A. D.; Ren, C.; Matsumoto, Y.; Nagao, S.; Yamanaka, M.; Hirota, S. 
\f4\i J. Inorg. Biochem. 2018, 182, 200-207.
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\outl0\strokewidth0 \strokec2 Construction of a Triangle-Shaped Trimer and a Tetrahedron Using an \uc0\u945 -Helix-Inserted Circular Permutant of Cytochrome 
\f4\i c
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\f4\i Chem. Asian J.
\f0\i0  2018, 13(8), 964-967. Featured on \'93Front Cover\'94.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Redox-dependent Conformational Changes of a Proximal [4Fe\'964S] Cluster in Hyb-type [NiFe]-hydrogenase to Protect the Active Site from O
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\f4\i Chem. Commun.
\f0\i0  2018, 54(87), 12385-12388.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Synergistic Effect of Distal Polar Interactions in Myoglobin and Their Structural Consequences\uc0\u8232 Watanabe, M.; Kanai, Y.; Nakamura, S.; Nishimura, R.; Shibata, T.; Momotake, A.; Yanagisawa, S.; Ogura, T.; Matsuo, T.; Hirota, S.; Neya, S.; Suzuki, A.; Yamamoto Y. 
\f4\i Inorg. Chem.
\f0\i0  2018, 57(22), 14269-14279.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews (International achievements only)
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\outl0\strokewidth0 \strokec2 Design of Artificial Metalloproteins/Metalloenzymes by Tuning Noncovalent Interactions \uc0\u8232 Hirota, S.; Lin, Y.-W. 
\f4\i J. Biol. Inorg. Chem.
\f0\i0  2018, 23(1), 7-25.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Comprehensive Reaction Mechanisms at and nearby the Ni
\f5 \uc0\u8210 
\f0 Fe Active Sites of [NiFe] Hydrogenases\uc0\u8232 Tai, H.; Higuchi, Y.; Hirota, S. Dalton Trans. (Perspective) 2018, 47(13), 4408-4423.\u8232 \
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\outl0\strokewidth0 \strokec2 Formation and Carbon Monoxide-Dependent Dissociation of 
\f4\i Allochromatium vinosum
\f0\i0  Cytochrome 
\f4\i c
\f0\i0 \'92 Oligomers Using Domain-Swapped Dimers\uc0\u8232 Yamanaka, M.; Hoshizumi, M.; Nagao, S.; Nakayama, R.; Shibata, N.; Higuchi, Y.; Hirota, S. 
\f4\i Protein Sci. 
\f0\i0 2017, 26(3), 464-474.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Improved Stopped-Flow Time-Resolved Resonance Raman Spectroscopy Device for Studying Enzymatic Reactions\uc0\u8232 Yanagisawa, S. Deshpande, M. S.; Hirota, S.; Nakagawa, T.; Ogura, T. 
\f4\i J. Raman Spectrosc. 
\f0\i0 2017, 48(5), 680-685.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Effect of Methionine80 Heme Coordination on Domain Swapping of Cytochrome 
\f4\i c
\f0\i0 \uc0\u8232 Hirota, S.; Yamashiro, N.; Wang, Z.; Nagao, S. 
\f4\i J. Biol. Inorg. Chem.
\f0\i0  2017, 22(5), 705-712. \uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 A Single Spherical Assembly of Protein Amyloid Fibrils Formed by Laser Trapping \uc0\u8232 Yuyama, K.; Ueda, M.; Nagao, S.; Hirota, S.; Sugiyama, T.; Masuhara, H. 
\f4\i Angew. Chem. Int. Ed.
\f0\i0  2017, 56(24), 6739-6743. Selected as "Hot Paper". \uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Structural Basis of the Redox Switches in the NAD+-Reducing Soluble [NiFe]-Hydrogenase \uc0\u8232 Shomura, Y.; Taketa, M.; Nakashima, H.; Tai, H.; Nakagawa, H.; Ikeda, Y.; Ishii, M.; Igarashi, Y.; Nishihara, H.; Yoon, K.-S.; Ogo, S.; Hirota, S.; Higuchi, Y. 
\f4\i Science
\f0\i0  2017, 357(6354), 928-932. \uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Rational Design of Domain-Swapping-Based 
\f4\i c
\f0\i0 -Type Cytochrome Heterodimers by Using Chimeric Proteins \uc0\u8232 Zhang, M.; Nakanishi, T.; Yamanaka, M.; Nagao, S.; Yanagisawa, S.; Shomura, Y.; Shibata, N.; Ogura, T.; Higuchi, Y.; Hirota, S. 
\f4\i ChemBioChem
\f0\i0  2017, 18(17), 1712-1715. \uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Equilibrium between Inactive Ready Ni-SIr and Active Ni-SIa States of [NiFe] Hydrogenase Studied by Utilizing Ni-SIr-to-Ni-SIa Photoactivation \uc0\u8232 Tai, H.; Xu, L.; Nishikawa, K.; Higuchi, Y.; Hirota, S. 
\f4\i Chem. Commun
\f0\i0  2017, 53(75), 10444-10447.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Activation Mechanism of Streptomyces Tyrosinase Assisted by the Caddie Protein\uc0\u8232 Matoba, Y.; Kihara, S.; Muraki, Y.; Bando, N.; Yoshitsu, H.; Kuroda, T.; Sakaguchi, M.; Kayama, K.; Tai, H.; Hirota, S.; Ogura, T.; Sugiyama, M. 
\f4\i Biochemistry
\f0\i0  2017, 56(41), 5593-5603.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Hydrophobicity of Residue 128 of the Stress-Inducible Sigma Factor RpoS Is Critical for Its Activity\uc0\u8232 Iwase, T.; Matsuo, T.; Nishioka, S.; Tajima, A.; Mizunoe, Y. 
\f4\i Front Microbiol
\f0\i0  2017, 8, 656. \uc0\u8232 \
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\outl0\strokewidth0 \strokec2 Domain swapping oligomerization of thermostable 
\f4\i c
\f0\i0 -type cytochrome in 
\f4\i E. coli
\f0\i0  cells\uc0\u8232 Hayashi, Y.; Yamanaka, M.; Nagao, S.; Komori, H.; Higuchi, Y.; Hirota, S. 
\f4\i Sci. Rep.
\f0\i0  2016, 6, 19334 (8 pages).\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Effect of Heme Electronic Structure and Distal Polar Interaction on Functional and Vibrational Properties of Myoglobin\uc0\u8232 Kanai, Y.; Nishimura, R.; Nishiyama, K.; Shibata, T. Yanagisawa, S.; Ogura, T.; Matsuo, T.; Hirota, S.; Neya, S.; Suzuki, A.; Yamamoto, Y. 
\f4\i Inorg. Chem.
\f0\i0  2016, 55, 1613-1622.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 A Simple Interfacial pH Detection Method for Cationic Amphiphilic Self-assemblies Utilizing a Schiff-base Molecule\uc0\u8232 Sarkar, Y. ; Das, S.; Ray, A.; Jewrajka, S. K.; Hirota, S.; Parui, P. P. 
\f4\i Analyst 
\f0\i0 2016, 141, 2030-2039.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Photoactivation of the Ni-SIr State to the Ni-SIa State in [NiFe] Hydrogenase: FT-IR Study on the Light Reactivity of the Ready Ni-SIr State and As-isolated Enzyme Revisited\uc0\u8232 Tai, H.; Xu, L.; Nishikawa, K.; Inoue, S.; Higuchi, Y.; Hirota, S. 
\f4\i Phys. Chem. Chem. Phys.
\f0\i0  2016, 18, 22025 - 22030.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Characterization of Cytochrome 
\f4\i c
\f0\i0  Membrane-Binding Site Using Cardiolipin-Containing Bicelles with NMR\uc0\u8232 Kobayashi, H.; Nagao, S.; Hirota, S. 
\f4\i Angew. Chem. Int. Ed. 
\f0\i0 2016, 55, 14019-14022.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Rational Design of Heterodimeric Protein Using Domain Swapping for Myoglobin\uc0\u8232 Lin, Y.-W.; Nagao, S.; Zhang, M.; Shomura, Y.; Higuchi, Y.; Hirota, S. 
\f4\i Angew. Chem. Int. Ed.
\f0\i0  2015, 54, 511-515.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Change in Structure and Ligand Binding Properties of Hyperstable Cytochrome 
\f4\i c
\f0\i0\fs20 \sub 555
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\f4\i Aquifex aeolicus
\f0\i0  by Domain Swapping\uc0\u8232 Yamanaka, M.; Nagao, S.; Komori, H.; Higuchi, Y.; Hirota, S. 
\f4\i Protein Sci.
\f0\i0  2015, 24, 366-375.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Carbon Monoxide Binding Properties of Domain-Swapped Dimeric Myoglobin Nagao, S.; Ishikawa, H.; Yamada, T.; Mizutani, Y.; Hirota, S.
\f4\i  J. Biol. Inorg. Chem.
\f0\i0  2015, 20, 253-530.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Dimer Domain Swapping 
\f4\i versus
\f0\i0  Monomer Folding in Apo-myoglobin Studied by Molecular Simulations\uc0\u8232 Ono, K.; Ito, M.; Hirota, S.; Takada, S. 
\f4\i Phys. Chem. Chem. Phys.
\f0\i0  2015, 17, 5006-5013.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Excimer Emission Properties on Pyrene-labeled Protein Surface: Correlation between Emission Spectra, Ring Stacking Modes and Flexibilities of Pyrene Probes\uc0\u8232 Fujii, A.; Sekiguchi, Y.; Matsumura, H.; Inoue, T.; Chung, WS.; Hirota, S.; Matsuo, T. 
\f4\i Bioconjugate Chem.
\f0\i0  2015, 26, 537-48.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Domain-Swapped Dimer of 
\f4\i Pseudomonas aeruginosa
\f0\i0  Cytochrome 
\f4\i c
\f0\i0\fs20 \sub 551
\fs24 \nosupersub : Structural Insights into Domain Swapping of Cytochrome 
\f4\i c
\f0\i0  Family Proteins\uc0\u8232 Nagao, S.; Ueda, M.; Osuka, H.; Komori, H.; Kamikubo, H.; Kataoka, M.; Higuchi, Y.; Hirota, S. 
\f4\i PLoS One
\f0\i0  2015, 10, e0123653.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Effect of a Procaspase-Activating Compound on the Catalytic Activity of Mature Caspase-3\uc0\u8232 Matsuo, T.; Yamada, K.; Ishida, M.; Miura, Y.; Yamanaka, M.; Hirota, S. 
\f4\i Bull. Chem. Soc. Jap.
\f0\i0  88, 2015, 1221-1229. BCSJ award\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Domain-swapped Cytochrome 
\f4\i cb
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\fs24 \nosupersub  Dimer and Its Nanocage Encapsulating a Zn\'96SO
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\fs24 \nosupersub  Cluster in the Internal Cavity\uc0\u8232 Miyamoto, T.; Kuribayashi, M.; Nagao, S.; Shomura, Y.; Higuchi, Y.; Hirota, S. 
\f4\i Chem. Sci. 
\f0\i0 2015, 6, 7336-7342.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Oligomerization Enhancement and Two Domain Swapping Mode Detection for Thermostable Cytochrome 
\f4\i c
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\fs24 \nosupersub  via the Elongation of the Major Hinge Loop\uc0\u8232 Ren, C.; Nagao, S.; Yamanaka, M.; Komori, H.; Shomura, Y.; Higuchi, Y., Hirota, S. 
\f4\i Mol. Biosyst.
\f0\i0  2015, 11, 3218-3221.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 FT-IR Characterization of the Light-Induced Ni-L2 and Ni-L3 States of [NiFe] Hydrogenase from 
\f4\i Desulfovibrio vulgaris
\f0\i0  Miyazaki F\uc0\u8232 Tai, H.; Nishikawa, K.; Inoue, S.; Higuchi, Y.; Hirota, S. 
\f4\i J. Phys. Chem. B
\f0\i0  2015, 119, 13668-13674.\uc0\u8232 \u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Self-Assembled Dimerization of Bis(crown ether)-2,2\'92-bibenzimidazoles\uc0\u8232 Satake, A.; Tanaka, K.; Asakura, H.; Okano, M.; Hashimoto, T,; Matsuura, Y.; Inaba, Y.; Oda, T.; Hirota, S.; Koshino, H. 
\f4\i Bull. Chem. Soc. Jpn
\f0\i0 . 2014, 87, 88-97. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Electronic Control of Discrimination between O
\fs20 \sub 2
\fs24 \nosupersub  and CO in Myoglobin the Lacking Distal Histidine Residue\uc0\u8232 Nishimura, R.; Shibata, T.; Ishigami, I.; Ogura, T.; Tai, H.; Nagao, S.; Matsuo, T.; Hirota, S.; Shoji, O.; Watanabe, Y.; Imai, K.; Neya, S.; Suzuki, A.; Yamamoto, Y. 
\f4\i Inorg. Chem.
\f0\i0  2014, 53, 1091\'961099. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 H
\fs20 \sub 2
\fs24 \nosupersub O
\fs20 \sub 2
\fs24 \nosupersub -dependent Substrate Oxidation by an Engineered Diiron Site in a Bacterial Hemerythrin\uc0\u8232 Okamoto, Y.; Onoda, A.; Sugimoto, H.; Takano, Y.; Hirota, S.; Kurtz, Jr., D. M.; Shiro, Y.; Hayashi T., 
\f4\i Chem. Commun.
\f0\i0  2014, 50, 3421-3423. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Morphological Change of Cell Membrane by Interaction with Domain-Swapped Cytochrome 
\f4\i c
\f0\i0  Oligomers \uc0\u8232 Junedi, S.; Yasuhara, K.; Nagao, S.; Kikuchi, J., Hirota, S. 
\f4\i ChemBioChem
\f0\i0  2014, 15, 517-521. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Formation of Domain-Swapped Oligomer of Cytochrome 
\f4\i c
\f0\i0  from Its Molten Globule State Oligomer\uc0\u8232 Deshpande, M. S.; Parui, P. P.; Kamikubo, H.; Yamanaka, M.; Nagao, S.; Komori, H.; Kataoka, M.; Higuchi, Y.; Hirota, S. 
\f4\i Biochemistry 
\f0\i0 2014, 53, 4696-4703.\uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Electronic Control of Ligand-Binding Preference of a Myoglobin Mutant\uc0\u8232 Nishimura, R.; Matsumoto, D.; Shibata, T.; Yanagisawa, S.; Ogura, T.; Tai, H.; Matsuo, T.; Hirota, S.; Neya, S.; Suzuki, A.; Yamamoto, Y. 
\f4\i Inorg. Chem.
\f0\i0  2014, 53, 9156-9165. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Self-Oxidation of Cytochrome 
\f4\i c
\f0\i0  at Methionine80 with Molecular Oxygen Induced by Cleavage of the Met\uc0\u8722 Heme Iron Bond\u8232 Wang, Z.; Ando, Y.; Nugraheni, A. D.; Ren, C.; Nagao, S.; Hirota, S. 
\f4\i Mol. BioSyst.
\f0\i0  2014, 10, 3130-3137. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 DNA Cleavage by Oxymyoglobin and Cysteine-Introduced Metmyoglobin\uc0\u8232 Deshpande, M. S.; Junedi, S.; Prakash, H.; Nagao, S.; Yamanaka, M.; Hirota, S.
\f4\i Chem. Commun.
\f0\i0  2014, 50, 15034-15036. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Control of the Transition between Ni-C and Ni-SIa States by the Redox State of the Proximal Fe-S Cluster in the Catalytic Cycle of [NiFe] Hydrogenase \uc0\u8232 Tai, H.; Nishikawa, K.; Suzuki, M.; Higuchi, Y.; Hirota, S., 
\f4\i Angew. Chem. Int. Ed.
\f0\i0  2014, 53, 13817-13820. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	10.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Structural characterization of imidazole adducts of heme-DNA complexes\uc0\u8232 Suzuki, Y.; Tai, H.; Saito, K.; Shibata, T.; Kinoshita, M.; Suzuki, A.; Yamamoto, Y., 
\f4\i J. Porphyrins Phthalocyanines
\f0\i0  2014, 18, 741-751. \uc0\u8232 \u8232 \
\ls17\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	11.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Effect of the electron density of the heme Fe atom on the Fe-histidine coordination bond in deoxy myoglobin\uc0\u8232 Nishimura, R.; Shibata, T.; Tai, H.; Ishigami, I.; Yanagisawa, S.; Ogura, T.; Neya, S.; Suzuki, A.; Yamamoto, Y., 
\f4\i Bull. Chem. Soc. Jpn.
\f0\i0  2014, 87, 905-911. \uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews
\f0\b0  (International achievements only)\uc0\u8232 \
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\outl0\strokewidth0 \strokec2 Artificial Enzymes with Protein Scaffolds: Structural Design and Modification\uc0\u8232 Matsuo, T.; Hirota, S. 
\f4\i Bioorg. Med. Chem.
\f0\i0  2014, 22, 5638-5656.\uc0\u8232 \
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\outl0\strokewidth0 \strokec2 Photosensitivity of the Ni-A state of [NiFe] hydrogenase from 
\f4\i Desulfovibrio vulgaris
\f0\i0  Miyazaki F with visible light\uc0\u8232 Osuka, H.; Shomura, Y.; Komori, H.; Shibata, N.; Nagao, S.; Higuchi, Y.; Hirota, S. 
\f4\i Biochem. Biophys. Res. Commun.
\f0\i0  
\f2\b 2013
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\f0\i0 , 284-288.\uc0\u8232 \u8232 \
\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Interaction of dimeric horse cytochrome 
\f4\i c
\f0\i0  with cyanide ion\uc0\u8232 Nugraheni, A.D.; Nagao, S.; Yanagisawa, S.; Ogura, T.; Hirota, S. 
\f4\i J. Biol. Inorg. Chem.
\f0\i0  
\f2\b 2013
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\f0\i0 , 383-390. \uc0\u8232 \u8232 \
\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Relationship between the electron density of the heme Fe atom and the vibrational frequencies of the Fe-bound carbon monoxide in myoglobin\uc0\u8232 Nishimura, R.; Shibata, T.; Tai, H.; Ishigami, I.; Ogura, T.; Nagao, S.; Matsuo, T.; Hirota, S.; Imai, K.; Neya, S.; Suzuki, A.; Yamamoto, Y.; 
\f4\i Inorg. Chem.
\f0\i0  
\f2\b 2013
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\f4\i 52
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\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Reversible switching of fluorophore property based on intrinsic conformational transition of adenylate kinase during its catalytic cycle\uc0\u8232 Fujii, A.; Hirota, S.; Matsuo, T. 
\f4\i Bioconjug. Chem.
\f0\i0  
\f2\b 2013
\f0\b0 , 
\f4\i 24
\f0\i0 , 1218-1225.\uc0\u8232 \u8232 \
\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Effect of Added Salt on Ring-closing Metathesis Catalyzed by a Water-soluble Hoveyda-Grubbs Type Complex to Form N-Containing Heterocycles in Aqueous Media\uc0\u8232 Matsuo, T.; Yoshida, T.; Fujii, A.; Kawahara, K.; Hirota, S. 
\f4\i Organometallics
\f0\i0  
\f2\b 2013
\f0\b0 , 
\f4\i 32
\f0\i0 , 5313-5319.\uc0\u8232 \u8232 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40
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\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Crystal Structure, Exogenous Ligand Binding and Redox Properties of an Engineered Diiron Active Site in a Bacterial Hemerythrin\uc0\u8232 Okamoto, Y.; Onoda, A.; Sugimoto, H.; Takano, Y.; Hirota, S.; Kurtz, Jr., D. M.; Shiro, Y,; Hayashi, T. 
\f4\i Inorg. Chem.
\f0\i0  
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\f0\b0 , 
\f4\i 52
\f0\i0 , 13014-13020.\uc0\u8232 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40\'81\'40
\f0 \uc0\u8232 \
\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Formation of Oligomeric Cytochrome 
\f4\i c
\f0\i0  during Folding by Intermolecular Hydrophobic Interaction between N- and C-Terminal \uc0\u945 -Helices\u8232 Parui, P. P.; Deshpande, M. S.; Nagao, S.; Kamikubo, H.; Komori, H.; Higuchi, Y.; Kataoka, M.; Hirota, S. 
\f4\i Biochemistry
\f0\i0  
\f2\b 2013
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\f0\i0 , 8732-8744.\uc0\u8232 \u8232 \
\ls19\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 NMR Spectroscopic Study of the Complexation Behaviors of Deuterated Cyclodextrins and [60]Fullerene\uc0\u8232 Ikeda, A.; Hida, T.; Kikuchi, J.; Nobusawa, K.; Matsuo, T.; 
\f4\i Org. Lett. 
\f2\i0\b 2013
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\f4\i 15
\f0\i0 , 6194-6197.\uc0\u8232 \u8232 \
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\outl0\strokewidth0 \strokec2 Creation of an Artificial Metalloprotein with a Hoveyda-Grubbs Catalyst Moiety through the Intrinsic Inhibition Mechanism of \uc0\u945 -Chymotrypsin\u8232 Matsuo, T.; Imai, C.; Yoshida, T.; Saito, T.; Hayashi, T. Hirota, S. 
\f4\i Chem. Commun.
\f0\i0  
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\f0\i0 , 1662-1664.\uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Structural and Oxygen Binding Properties of Dimeric Horse Myoglobin\uc0\u8232 Nagao, S.; Osuka, H.; Yamada, T.; Uni, T.; Shomura, Y.; Higuchi, Y.; Hirota, S. 
\f4\i Dalton Trans. 
\f2\i0\b 2012
\f0\b0 , 
\f4\i 41
\f0\i0 , 11378-11385. \uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Domain Swapping of the Heme and N-terminal \uc0\u945 -helix in 
\f4\i Hydrogenobacter thermophilus
\f0\i0  Cytochrome 
\f4\i c
\f0\i0\fs20 \sub 552
\fs24 \nosupersub  Dimer\uc0\u8232 Hayashi, Y.; Nagao, S.; Osuka, H.; Komori, H.; Higuchi, Y.; Hirota, S. 
\f4\i Biochemistry
\f0\i0  
\f2\b 2012
\f0\b0 , 
\f4\i 51
\f0\i0 , 8608-8616. \uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Relationship between Oxygen Affinity and Autoxidation of Myoglobin\uc0\u8232 Shibata, T.; Matsumoto, D.; Nishimura, R.; Tai, H.; Matsuoka, A.; Nagao, S.; Matsuo, T.; Hirota, S.; Imai, K.; Neya, S.; Suzuki, A.; Yamamoto, Y. 
\f4\i Inorg. Chem.
\f0\i0  
\f2\b 2012
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\f0\i0 , 11955-11960.\uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Efficient Oxidative Cycloreversion Reaction of Photochromic Dithiazolythiazole\uc0\u8232 Nakashima, T.; Kajiki, Y.; Fukumoto, S.; Taguchi, M.; Nagao, S.; Hirota, S.; Kawai, T. 
\f4\i J. Am. Chem. Soc.
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\f0\i0 , 19877-19883. \uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Maintenance of the Secondary Structure of Horse Cytochrome 
\f4\i c
\f0\i0  during the Conversion Process of Monomers to Oligomers by Addition of Ethanol\uc0\u8232 Hirota, S.; Ueda, M.; Hayashi, Y.; Nagao, S.; Kamikubo, H.; Kataoka, M. 
\f4\i J. Biochem.
\f0\i0  
\f2\b 2012
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\f0\i0 , 521-529.\uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Field-dependent 
\fs20 \super 19
\fs24 \nosupersub F NMR Study of Sperm Whale Myoglobin Reconstituted with Ring-fluorinated Heme\uc0\u8232 Yamamoto, Y.; Nagao, S.; Hirai, Y.; Tai, H.; Suzuki, A. 
\f4\i Polymer J.
\f0\i0  
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\f0\i0 , 907-912. \uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Reaction Pathway and Free Energy Profile for Conversion of pi-Conjugation Modes in Porphyrin Isomer\uc0\u8232 Matsuo, T.; Tohi, Y.; Hayashi, T. 
\f4\i J. Org. Chem.
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\f0\i0 , 8946-8955.\uc0\u8232 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40
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\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Reaction of Cobalt Porphycene with Hydride Reagents: Spectroscopic Detection of Co\'96H Porphycene Species and Formation of Co\'96SnR
\fs20 \sub 3
\fs24 \nosupersub  Porphycene Species\uc0\u8232 Matsuo, T.; Komatsuzaki, K.; Tsuji, T.; Hayashi, T. 
\f4\i J. Pophyrins. Phthalocyanines.
\f0\i0  
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\f0\i0 , 616-625.\uc0\u8232 \u8232 \
\ls20\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	10.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Synthesis of Rhenium(I) Tricarbonyl Complexes with Carbohydrate-Pendant Tridentate Ligands and their Cellular Uptake\uc0\u8232 Mikata, Y.; Takahashi, K.; Noguchi, Y.; Naemura, M.; Ugai, A.; Itami, S.; Yasuda, K.; Tamotsu, S.; Matsuo, T.; Storr, T. 
\f4\i Eur.J. Inorg. Chem.
\f0\i0  
\f2\b 2012
\f0\b0 , 217-225.\uc0\u8232 \u8232 \
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\f2\b Original papers
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\outl0\strokewidth0 \strokec2 Supramolecular Organization of Light-Harvesting Porphyrin Macrorings\uc0\u8232 Satake, A.; Azuma, S.; Kuramochi, Y.; Hirota, S.; Kobuke, Y. 
\f4\i Chem. Eur. J.
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\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Enhancement of Laccase Activity through the Construction and Breakdown of a Hydrogen Bond at the Type I Copper Center in Escherichia coli CueO and the Deletion Mutant \uc0\u916 \u945 5-7 CueO\u8232 Kataoka, K.; Hirota, S.; Maeda, Y.; Kogi, H.; Shinohara, N.; Sekimoto, M.; Sakurai, T. 
\f4\i Biochemistry
\f0\i0  
\f2\b 2011
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\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Post-translational His-Cys Cross-Linkage Formation in Tyrosinase Induced by Copper(II)-Peroxo Species\uc0\u8232 Fujieda, N.; Ikeda, T.; Murata, M.; Yanagisawa, S.; Aono, S.; Okubo, K.; Nagao, S.; Ogura, T.; Hirota, S.; Fukuzumi, S.; Nakamura, Y.; Hata, Y.; Itoh, S. 
\f4\i J. Am. Chem. Soc.
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\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Efficient Reduction of Cys110 Thiyl Radical by Glutathione in Human Myoglobin\uc0\u8232 Nagao, S.; Asami, O.; Yasui, H.; Hirota, S. 
\f4\i Biochim. Biophys. Acta \'96 Proteins and Proteomics
\f0\i0  
\f2\b 2011
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\f0\i0 , 480-486.\uc0\u8232 \u8232 \
\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Peroxidase Activity Enhancement of Horse Cytochrome 
\f4\i c
\f0\i0  by Dimerization\uc0\u8232 Wang, Z.; Matsuo, T.; Nagao, S.; Hirota, S. 
\f4\i Org. Biomol. Chem.
\f0\i0  
\f2\b 2011
\f0\b0 , 
\f4\i 9
\f0\i0 , 4766-4769.\uc0\u8232 \u8232 \
\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 DNA Cleavage by the Photocontrolled Cooperation of ZnII Centers in an Azobenzene-Linked Dizinc Complex\uc0\u8232 Panja, A.; Matsuo, T.; Nagao, S.; Hirota, S. 
\f4\i Inorg. Chem.
\f0\i0  
\f2\b 2011
\f0\b0 , 
\f4\i 50
\f0\i0 , 11437-11445.\uc0\u8232 \u8232 \
\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Thermal Isomerization of N-Bridged Cobalt Corrole Complexes through Transiently Formed Axial Carbenoid\uc0\u8232 Chattopadhyay, P.; Matsuo, T; Tsuji, T.; Ohbayashi, J.; Hayashi, T. 
\f4\i Organometallics
\f0\i0  
\f2\b 2011
\f0\b0 , 
\f4\i 30
\f0\i0 , 1869-1873.\uc0\u8232 \u8232 \
\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Precise Design of Artificial Cofactors for Enhancing Peroxidase Activity of Myoglobin: Myoglobin Mutant H64D Reconstituted with a Single-winged Cofactor is Equivalent to Native Horseradish Peroxidase in Oxidation Activity\uc0\u8232 Matsuo, T; Fukumoto, K.; Watanabe, T.; Hayashi, T. 
\f4\i Chem. Asian. J.
\f0\i0  
\f2\b 2011
\f0\b0 , 
\f4\i 6
\f0\i0 , 2491-2499. [INSIDE COVER FIGURE]\uc0\u8232 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40
\f0  \uc0\u8232 \
\ls21\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Investigation of Aromaticity and Photophysical Properties in [18]/[20]pi-Porphycene Derivatives\uc0\u8232 Kim, K. S.; Sung, Y. M.; Matsuo, T.; Hayashi, T.; Kim, D. 
\f4\i Chem. Eur. J.
\f0\i0  
\f2\b 2011
\f0\b0 , 
\f4\i 17
\f0\i0 , 7882-7889.\uc0\u8232 
\f1 \'81\'40\'81\'40\'81\'40\'81\'40
\f0  \uc0\u8232 \u8232 \
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\f2\b \cf2 2010
\f0\b0 \
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\f2\b Original papers
\f0\b0 \
\pard\intbl\itap3\tx220\tx720\pardeftab720\li720\fi-720\partightenfactor0
\ls22\ilvl0\cf2 \kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	1.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Supramolecular Protein\'96Protein Complexation via Specific Interaction Between Glycosylated Myoglobin and Sugar-binding Protein\uc0\u8232 Nagai, H.; Onoda, A.; Matsuo, T.; Hayashi, T. 
\f4\i Supramol. Chem.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 22
\f0\i0 , 57-64.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten\'96Containing Enzyme (WOR4) from Pyrococcus furiosus\uc0\u8232 Sugimoto, H.; Tano, H.; Toyota, K.; Tajima, R.; Miyake, H.; Takahashi, I.; Hirota, S.; Itoh, S. 
\f4\i J. Am. Chem. Soc.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 132
\f0\i0 , 8-9.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Effect of Heme Modification on Oxygen Affinity of Myoglobin and Equilibrium of the Acid-Alkaline Transition in Metmyoglobin\uc0\u8232 Shibata, T.; Nagao, S.; Fukaya, M.; Tai, H.; Nagatomo, S.; Morihashi, K.; Matsuo, T.; Hirota, S.; Suzuki, A.; Imai, K.; Yamamoto, Y. 
\f4\i J. Am. Chem. Soc.
\f0\i0  
\f2\b 2010
\f0\b0 , 
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\f0\i0 , 6091-6098.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Coherent Dynamics and Ultrafast Excited State Relaxation of Blue Copper Protein; Plastocyanin\uc0\u8232 Nagasawa, Y.; Fujita, K.; Katayama, T.; Ishibashi, Y.; Miyasaka, H.; Takabe, T.; Nagao, S; Hirota, S. 
\f4\i Phys. Chem. Chem. Phys.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 12
\f0\i0 , 6067-6075.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Structural Basis of the Lactate-Dependent Allosteric Regulation of Oxygen Binding in Arthropod Hemocyanin\uc0\u8232 Hirota, S.; Tanaka, N.; Micetic, I.; Di Muro, P.; Nagao, S.; Kitagishi, H.; Kano, K.; Magliozzo, R. S.; Peisach, J.; Beltramini, M.; Bubacco, L. 
\f4\i J. Biol. Chem.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 285
\f0\i0 , 19338-19345.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Characterization of the Acid\'96alkaline Transition in the Individual Subunits of Human Adult and Foetal Methaemoglobins\uc0\u8232 Shibata, T.; Nagao, S.; Tai, H.; Nagatomo, S.; Hamada, H.; Yoshikawa, H.; Suzuki, A.; Yamamoto, Y. 
\f4\i J. Biochem.
\f0\i0  
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\f0\b0 , 
\f4\i 148
\f0\i0 , 217-229.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Cytochrome 
\f4\i c
\f0\i0  Polymerization by Successive Domain Swapping at the C-Terminal Helix\uc0\u8232 Hirota, S.; Hattori, Y.; Nagao, S. Taketa, M.; Komori, H.; Kamikubo, H.; Wang, Z.; Takahashi, I.; Negi, S.; Sugiura, Y.; Kataoka, M.; Higuchi, Y. 
\f4\i Proc. Natl. Acad. Sci. USA
\f0\i0  
\f2\b 2010
\f0\b0 , 
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\f0\i0 , 12854-12859.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Crystallization and Preliminary X-ray Analysis of Dimeric and Trimeric Cytochromes 
\f4\i c
\f0\i0  from horse Heart\uc0\u8232 Taketa, M.; Komori, H.; Hattori, Y.; Nagao, S.; Hirota, S.; Higuchi, Y. 
\f4\i Acta. Crystallogr. Sect. F
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 66
\f0\i0 , 1477-1479.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 New Class of Rhodamine Luminophore: Design, Syntheses and Aggregation-Induced Emission Enhancement\uc0\u8232 Kamino, S.; Horio, Y.; Komeda, S.; Minoura, K.; Ichikawa, H.; Horigome, J.; Tatsumi, A.; Kaji, S.; Yamaguchi, T.; Usami, Y.; Hirota, S.; Enomoto, S.; Fujita, Y. 
\f4\i Chem. Commun.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 46
\f0\i0 , 9013-9015.\uc0\u8232 \u8232 \
\ls22\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	10.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Oxoferryl Porphyrin/Hydrogen Peroxide System Whose Behavior is Equivalent to Hydroperoxoferric Porphyrin\uc0\u8232 Kitagishi, H.; Tamaki, M.; Ueda, T.; Hirota, S.; Ohta, T.; Naruta, Y.; Kano, K. 
\f4\i J. Am. Chem. Soc.
\f0\i0  
\f2\b 2010
\f0\b0 , 
\f4\i 132
\f0\i0 , 16730\'9616732.\uc0\u8232 \u8232 \
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\f2\b \cf2 2009
\f0\b0 \
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\f2\b Original papers
\f0\b0 \
\pard\intbl\itap3\tx220\tx720\pardeftab720\li720\fi-720\partightenfactor0
\ls23\ilvl0\cf2 \kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	1.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 A Role of the Heme-7-Propionate Side Chain in Cytochrome P450cam as a Gate for Regulating the Access of Water Molecules to the Substrate-Binding Site\uc0\u8232 Hayashi, T.; Harada, K.; Sakurai, K.; Shimada, H.; Hirota, S. 
\f4\i J. Am. Chem. Soc.
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\f0\i0 , 1398-1400.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Four-Electron Reduction of Dioxygen by a Multicopper Oxidase, CueO, and Roles of Asp112 and Glu506 Located Adjacent to the Trinuclear Copper Center\uc0\u8232 Kataoka, K.; Sugiyama, R.; Hirota, S.; Inoue, M.; Urata, K; Minagawa, Y.; Seo, D.; Sakurai, T. 
\f4\i J. Biol. Chem.
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\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Modulation of Protein-Ligand Interactions by Photocleavage of a Cyclic Peptide using Phosphatidylinositol 3-Kinase SH3 Domain as Model System\uc0\u8232 Takahashi, I.; Kuroiwa, S.; Lindfors, H.; Ndamba, L. A.; Hiruma, Y.; Yajima, T.; Okishio, N.; Ubbink, M.; Hirota, S. 
\f4\i J. Petp. Sci.
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\f0\i0 , 411-416.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Electron Transfer from Cytochrome c to Cupredoxin\uc0\u8232 Takayama, S. J.; Irie, K.; Tai, H.; Kawahara, T.; Hirota, S.; Takabe, T.; Alcaraz, J. A.; Donaire, A.; Yamamoto, Y. 
\f4\i J. Biol. Inorg. Chem.
\f0\i0  
\f2\b 2009
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\f0\i0 , 821-828.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Regulating Copper-Binding Affinity with Photoisomerizable Azobenzene Ligand by Construction of a Self-Assembled Monolayer\uc0\u8232 Takahashi, I; Honda, Y.; Hirota, S. 
\f4\i Angew. Chem. Int. Ed.
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\f2\b 2009
\f0\b0 , 
\f4\i 48
\f0\i0 , 6065-6068.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Coordination-induced sliding motion of a complementary porphyrin-phthalocyanine dimer: fluorescence-based molecular switch\uc0\u8232 Satake, A.; Sugimura, T.; Kobuke, Y. 
\f4\i J. Porphyrins Phthalocyanines
\f0\i0  
\f2\b 2009
\f0\b0 , 
\f4\i 13
\f0\i0 , 326-335.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Energy transfer followed by electron transfer in a porphyrin macrocycle and central acceptor ligand: A model for a photosynthetic composite of the light-harvesting complex and reaction center\uc0\u8232 Kuramochi, Y.; Sandanayaka, Atula S. D.; Satake, A.; Araki, Y.; Ogawa, K.; Ito, O.; Kobuke, Y. 
\f4\i Chem. Eur. J.
\f0\i0  
\f2\b 2009
\f0\b0 , 
\f4\i 15
\f0\i0 , 2317-2327.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Single Supramolecular Porphyrin Wires Bridging Gold Nanoparticles\uc0\u8232 Satake, A.; Fujita, M.; Kurimoto, Y.; Kobuke, Y. 
\f4\i J. Inorg. Chem.
\f0\i0  
\f2\b 2009
\f0\b0 , 1231-1233.\uc0\u8232 \u8232 \
\ls23\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Meso-Unsubstituted Iron Corrole in Hemoproteins: Remarkable Differences in Effects on Peroxidase Activities
\f1 \'81\'40
\f0 between Myoglobin and Horseradish Peroxidase\uc0\u8232 Matsuo, T.; Hayashi, A.; Abe, M.; Matsuda, T.; Hisaeda Y.; Hayashi, T. 
\f4\i J. Am. Chem. Soc.
\f0\i0  
\f2\b 2009
\f0\b0 , 
\f4\i 131
\f0\i0 , 15124-15125.\uc0\u8232 \u8232 \
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\f2\b \cf2 Reviews 
\f0\b0 (International achievements only)\
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\ls24\ilvl0\cf2 \kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	1.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Electron Transfer and Oxidation Activities in Reconstituted Hemoproteins
\f1 \'81\'40
\f0 with Chemically Modified Cofactor\uc0\u8232 Matsuo, T.; Hayashi, T. 
\f4\i J. Porphyrins Phthalocyanines
\f0\i0  
\f2\b 2009
\f0\b0 , 
\f4\i 13
\f0\i0 , 1082-1089.\uc0\u8232 \u8232 \
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\f2\b \cf2 2008
\f0\b0 \
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\f2\b Original papers
\f0\b0 \
\pard\intbl\itap3\tx220\tx720\pardeftab720\li720\fi-720\partightenfactor0
\ls25\ilvl0\cf2 \kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	1.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Evaluation of the Functional Role of the Heme-6-Propionate Side Chain in Cytochrome P450cam\uc0\u8232 Harada, K.; Sakurai, K.; Ikemura, K.; Ogura, T.; Hirota, S.; Shimada, H.; Hayashi, T. 
\f4\i J. Am. Chem. Soc.
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\f2\b 2008
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\f0\i0 , 432-433.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	2.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 H-atom Abstraction Reaction for Organic Substrates via Mononuclear Copper(II)-Superoxo Species as a Model for DbM and PHM\uc0\u8232 Fujii, T.; Yamaguchi, S.; Hirota, S.; Masuda, H. 
\f4\i Dalton Trans
\f0\i0  
\f2\b 2008
\f0\b0 , 164-170.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	3.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Development of Novel Water-Soluble Photocleavable Protective Group and Its Application for Design of Photoresponsive Paclitaxel Prodrugs\uc0\u8232 Noguchi, M.; Skwarczynski, M.; Prakash, H.; Hirota, S.; Kimura, T.; Hayashi, Y.; Kiso, Y. 
\f4\i Bioorg. Med. Chem
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\f2\b 2008
\f0\b0 , 
\f4\i 16
\f0\i0 , 5389-5397.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	4.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Thermodynamics of Apoplastocyanin Folding: Comparison between Experimental and Theoretical Results\uc0\u8232 Yoshidome, T.; Kinoshita, M.; Hirota, S.; Baden, N.; Terazima, M. 
\f4\i J. Chem. Phys.
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\f2\b 2008
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\f0\i0 , 225104.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	5.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Photocontrol of Spatial Orientation and DNA Cleavage Activity of Copper(II)-Bound Dipeptides Linked by an Azobenzene Derivative\uc0\u8232 Prakash, H.; Shodai, A.; Yasui, H.; Sakurai, H.; Hirota, S. 
\f4\i Inorg. Chem.
\f0\i0  
\f2\b 2008
\f0\b0 , 
\f4\i 47
\f0\i0 , 5045-5047.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	6.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 A Supramolecular Receptor of Diatomic Molecules (O2, CO, NO) in Aqueous Solution \uc0\u8232 Kano, K.; Itoh, Y.; Kitagishi, H.; Hayashi, T.; Hirota, S. 
\f4\i J. Am. Chem. Soc.
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\f2\b 2008
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\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	7.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Stable Supramolecular Complex of Porphyrin Macroring with Pyridyl and Fullerenyl Ligands\uc0\u8232 Zafer, U.; Satake, A.; Kobuke, Y.; Hirota, S. 
\f4\i Tetrahedron Lett.
\f0\i0  
\f2\b 2008
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\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	8.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Syntheses, Characterization and Reactivities of \uc0\u956 -\u951 2:\u951 2-Disulfidodicopper(II) Complexes with N-Alkylated cis,cis-1,3,5-Triamionocyclohexane Derivatives\u8232 Kajita, Y.; Matsumoto, J.; Takahashi, I.; Hirota, S.; Funahashi, Y.; Ozawa, T.; Masuda, H., Eur. 
\f4\i J. Inorg. Chem
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\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	9.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 A New Class of Sulfido/oxo(dithiolene)\'96molybdenum(IV) Complexes Derived from Sulfido/Oxo\'96Bis(tetrasulfido)molydebnum(IV) Anions\uc0\u8232 Sugimoto, H.; Suyama, K.; Sugimoto, K.; Miyake, H.; Takahashi, I.; Hirota, S.; Itoh, S. 
\f4\i Inorg. Chem.
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\f2\b 2008
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\f0\i0 , 10150-10157.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	10.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Molecular Basis of the Bohr Effect in Arthropod Hemocyanin \uc0\u8232 Hirota, S.; Kawahara, T.; Beltramini, M.; Di Muro, P.; Magliozzo, R. S.; Peisach, J.; Powers, L. S.; Tanaka, N.; Nagao, S.; Bubacco, L. 
\f4\i J. Biol. Chem.
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\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	11.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Construction of Giant Porphyrin Macrorings Self-Assembled from Thiophenylene-Linked Bisporphyrins for Light-Harvesting Antenna\uc0\u8232 Fujisawa, K.; Satake, A.; Hirota, S.; Kobuke, Y. 
\f4\i Chem. Eur. J.
\f0\i0  
\f2\b 2008
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\f0\i0 , 10735-10744.\uc0\u8232 \u8232 \
\ls25\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	12.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Formation of a Bridged Butterfly-Type \uc0\u956 -\u951 2:\u951 2-Peroxo Dicopper Core Structure with a Carboxylate Group\u8232 Funahashi, Y.; Nishikawa, T.; Wasada-Tsutsui, Y.; Kajita, Y.; Yamaguchi, S.; Arii, H.; Ozawa, T.; Jitsukawa, K.; Tosha, T.; Hirota, S.; Kitagawa, T.; Masuda, H. 
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\outl0\strokewidth0 \strokec2 Controlled Production of Amyloid \uc0\u946  Peptide from a Photo-Triggered, Water-Soluble Precursor "Click Peptide"\u8232 Taniguchi, A.; Skwarczynski, M.; Sohma, Y.; Okada, T.; Ikeda, K.; Prakash, H.; Mukai, H.; Hayashi, Y.; Kimura, T.; Hirota, S.; Matsuzaki, K.; Kiso, Y. 
\f4\i ChemBioChem
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\outl0\strokewidth0 \strokec2 Oxidation of Adamantane Catalysed by Imidazolylporphyrinatoiron(III) Complexes and Structural Studies of 5-Coordinating Iron(III) Porphyrin, \uc0\u8232 Miyazaki, Y.; Satake, A.; Kobuke, Y. 
\f4\i J. Mol. Cat. A: Chemical
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\outl0\strokewidth0 \strokec2 Light-Harvesting Supramolecular Porphyrin Macroring Accommodating a Fullerene\'96Tripodal Ligand, \uc0\u8232 Kuramochi, Y.; Satake, A.; Itou, M.; Ogawa, K.; Araki, Y.; Ito, O.; Kobuke, Y. 
\f4\i Chem. Eur. J.
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\outl0\strokewidth0 \strokec2 Transmembrane Nanopores from Porphyrin Supramolecules\uc0\u8232 Satake, A.; Yamamura, M.; Oda, M.; Kobuke, Y. 
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\outl0\strokewidth0 \strokec2 Recent Advances in Two-photon Photodynamic Therapy\uc0\u8232 Ogawa, K.; Kobuke, Y. 
\f4\i Curr. Med. Chem. - Anti-Cancer Agents
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\outl0\strokewidth0 \strokec2 Stepwise Elongation Effect on the Two-photon Absorption of Self-assembled Butadiyne Porphyrins\uc0\u8232 Dy, J. T.; Ogawa, K.; Kamada, K.; Ohta, K; Kobuke, Y. 
\f4\i Chem. Commun.
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\outl0\strokewidth0 \strokec2 Structure and Ligand Binding Properties of Myoglobins Reconstituted with Monodepropionated Heme: Functional Role of Each Heme-Propionate Side Chain\uc0\u8232 Harada, K.; Makino, M.; Sugimoto, H.; Hirota, S.; Matsuo, T.; Shiro, Y.; Hisaeda, Y.; Hayashi, T. 
\f4\i Biochemistry
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\outl0\strokewidth0 \strokec2 Trapping of a Dopaquinone Intermediate in the TPQ Cofactor Biogenesis in a Copper-containing Amine Oxidase from 
\f4\i Arthrobacter globiformis
\f0\i0 \uc0\u8232 Moore, R. H.; Spies, M. A.; Culpepper, M. B.; Murakawa, T.; Hirota, S.; Okajima, T.; Tanizawa, K.; Mure, M. 
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\outl0\strokewidth0 \strokec2 Thermodynamical Properties of Reaction Intermediates during Apoplastocyanin Folding in Time-Domain\uc0\u8232 Baden, N.; Hirota, S.; Takabe, T.; Funasaki, N.; Terazima, M. 
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\outl0\strokewidth0 \strokec2 A Photochromic Porphyrin-perinaphthothioindigo Conjugate and its Two-photon Absorption Properties\uc0\u8232 Dy, J. T.; Maeda, R.; Nagatsuka, Y.; Ogawa, K.; Kamada, K.; Ohta, K.; Kobuke, Y.\'a0 
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\outl0\strokewidth0 \strokec2 Syntheses and Properties of Acetylene-linked Bis- and Trisporphyrins toward Two-photon Photodynamic Therapy\uc0\u8232 Inaba, Y.; Ogawa, K.; Kobuke, Y. 
\f4\i J. Porphyrins Phthalocyanines
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\outl0\strokewidth0 \strokec2 Ligand-Induced Interconversion of a Coordination-Organized Porphyrin Dimer: a Potential Fluorescence-based Molecular Memory Monitor, \uc0\u8232 Satake, A.; Tanihara, J.; Kobuke, Y. 
\f4\i Inorg. Chem.
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\outl0\strokewidth0 \strokec2 Water-soluble Self-assembled Butadiyne-bridged Bisporphyrin: a Potential Two- Photon Absorbing Photosensitizer for Photodynamic Therapy\uc0\u8232 Dy, J.; K. Ogawa, K.; Satake, A.; Ishizumi, A.; Kobuke, Y. 
\f4\i Chem. Eur. J.
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\outl0\strokewidth0 \strokec2 Singlet Oxygen Generation and Photocytotoxicity against Tumor Cell by Two-Photon Absorption\uc0\u8232 Ogawa, K.; Dy, J.; Kobuke, Y.; Ogura, S.; Okura, I. 
\f4\i Mol. Cryst. Liq. Cryst. 
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\outl0\strokewidth0 \strokec2 Supramolecular Array of Imizazolylethynyl-zinc-porphyrin,\uc0\u8232 Satake, A.; Shoji, O.; Kobuke, Y. 
\f4\i J. Organomet. Chem.
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\outl0\strokewidth0 \strokec2 Heme Orientational Disorder in Human Adult Hemoglobin Reconstituted with a Ring Fluorinated Heme and Its Functional Consequences\uc0\u8232 Nagao S.; Hirai Y.; Kawano S.; Imai K.; Suzuki A.; Yamamoto Y. 
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\outl0\strokewidth0 \strokec2 Chemical Shifts as a Novel Measure of Interactions between Two Binding Sites of Symmetric Dialkyldimethylammonium Bromides to \uc0\u945 -Cyclodextrin\u8232 Funasaki, N.; Ishikawa, S.; Hirota, S. 
\f4\i Anal. Chim. Acta
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\outl0\strokewidth0 \strokec2 "Click Peptide" Based on the "
\f4\i O
\f0\i0 -Acyl Isopeptide Method": Control of A\uc0\u946 1-42 Production from a Photo-Triggered A\u946 1-42 Analogue\u8232 Taniguchi, A.; Sohma, Y.; Kimura, M.; Okada, T.; Ikeda, K.; Hayashi, Y.; Kimura, T.; Hirota, S.; Matsuzaki, K.; Kiso, Y. 
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\f4\i Chem. Pharm. Bull.
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\outl0\strokewidth0 \strokec2 Kinetic and Structural Studies on the Catalytic Role of the Aspartic Acid Residue Conserved in Copper Amine Oxidase\uc0\u8232 Chiu, Y.-C.; Okajima, T.; Murakawa, T.; Uchida, M.; Taki, M.; Hirota, S.; Kim, M.; Yamaguchi, H.; Kawano, Y.; Kamiya, N.; Kuroda, S.; Hayashi, H.; Yamamoto, Y.; Tanizawa, K. 
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\outl0\strokewidth0 \strokec2 Iron Porphyrin-Cyclodextrin Supramolecular Complex as a Functional Model of Myoglobin in Aqueous Solution\uc0\u8232 Kano, K.; Kitagishi, H.; Dagallier, C.; Kodera, M.; Matsuo, T.; Hayashi, T.; Hisaeda, Y.; Hirota, S. 
\f4\i Inorg. Chem.
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\outl0\strokewidth0 \strokec2 Micelle Formation of Bile Salts and Zwitterionic Derivative as Studied by Two-Dimensional NMR Spectroscopy\uc0\u8232 Funasaki, N.; Fukuba, M.; Hattori, T.; Ishikawa, S.; Okuno, T.; Hirota S. 
\f4\i Chem. Phys. Lipids
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\outl0\strokewidth0 \strokec2 Masking Mechanisms of Bitter Taste of Drugs Studied with Ion Selective Electrodes\uc0\u8232 Funasaki, N.; Uratsuji, I.; Okuno, T.; Hirota, S.; Neya, S. 
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\f0\i0 -acyl isopeptide method\'92 for peptide synthesis and chemical biology-oriented synthesis of amyloid \uc0\u946 peptide analoguesShoma, Y.; Taniguchi, A.; Yoshiya, T.; Chiyomori, Y.; Fukao, F.; Nakamura, S.; Skwarczynski, M.; Okada, T.; Ikeda, K.; Hayashi, Y.; Kimura, T.; Hirota, S.; Matsuzaki, K.; Kiso, Y. 
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\outl0\strokewidth0 \strokec2 Direct Observation of Photoinduced Electron Transfer in Zinc Porphyrin / Zinc Phthalocyanine Composite\uc0\u8232 Ito, F.; Ishibashi, Y.; Khan, S. R.; Miyasaka, H.; Kameyama, K.; Morisue, M.; Satake, A.; Ogawa, K.; Kobuke, Y. 
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\f4\i Chem. Commun.
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\f4\i Chem. Commun.
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\outl0\strokewidth0 \strokec2 Two-photon Absorption Properties of Conjugated Supramolecular Porphyrins with Electron Donor and Acceptor\uc0\u8232 Tanihara, J.; Ogawa, K.; Kobuke, Y. 
\f4\i J. Photochem. Photobiol. A 
\f2\i0\b 2006
\f0\b0 , 
\f4\i 178
\f0\i0 , 140-149.\uc0\u8232 \u8232 \
\ls28\ilvl0\kerning1\expnd0\expndtw0 \outl0\strokewidth0 {\listtext	20.	}\expnd0\expndtw0\kerning0
\outl0\strokewidth0 \strokec2 Synthesis of Hexazincporphyrin and Hexaamine Substituted Ru(bipy)3 Complexes for Alternate Self-Assembly by Tritopic Coordinations\uc0\u8232 Fukuda, S.; Satake, A.; Kobuke, Y. 
\f4\i Thin Solid Films 
\f2\i0\b 2006
\f0\b0 , 
\f4\i 499
\f0\i0 , 263-268.\
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\f2\b \cf2 Review
\f0\b0  (International achievements only)\
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\fs24 \nosupersub F NMR Study of 
\f4\i b
\f0\i0 -Type Haemoproteins\uc0\u8232 Yamamoto Y; Nagao S.; Suzuki A. Modern Magnetic Resonance, Webb, G. A. Ed., Springer, 
\f2\b 2006
\f0\b0 , pp.527-534.\
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